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Quasiparticle peak in angle-integrated PES spectrum of V2O3

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Inquiry number

SOL-0000000959

Beamline

BL25SU (Soft X-ray Spectroscopy of Solid)

Scientific keywords

A. Sample category inorganic material
B. Sample category (detail) metal, alloy, insulator, ceramics, solid-state crystal, crystal
C. Technique photoemission, photoionization
D. Technique (detail) photoelectron spectra
E. Particular condition ultra-high vacuum, low-T (~ liquid N2)
F. Photon energy soft X-ray
G. Target information electronic state

Industrial keywords

level 1---Application area Semiconductor
level 2---Target silicon semiconductor, compound semiconductor
level 3---Target (detail)
level 4---Obtainable information electronic state
level 5---Technique XPS

Classification

M40.40 soft x-ray spectroscopy, M50.10 photoelectron spectroscopy

Body text

Angle-integrated photoemission spectroscopy is a powerful tool to investigate density of states of valence electronic states in solids. Photoemission spectra in the soft x-ray region are more bulk sensitive than those in the ultra violet region, because escape depths of photoelectrons become larger with increasing the excitation energy. The figure shows excitation energy dependence of valence photoemission spectra for V2O3. A quasiparticle peak is clearly observed by the soft x-ray photoemission spectroscopy.

 

[ S.-K. Mo, J. D. Denlinger, H.-D. Kim, J.-H. Park, J. W. Allen, A. Sekiyama, A. Yamasaki, K. Kadono, S. Suga, Y. Saitoh, T. Muro, P. Metcalf, G. Keller, K. Held, V. Eyert, V. I. Anismov and D. Vollhardt, Physical Review Letters 90, 186403 (2003), Fig. 2,
©2003 American Physical Society ]

Source of the figure

Original paper/Journal article

Journal title

Phys. Rev. Lett.90, 186403 (2003)

Figure No.

2

Technique

Soft x-ray photoemission spectroscopy provides information of valence electronic states of solids. Photoelectrons emitted by illumination of soft x-rays are analyzed with a hemispherical electron analyzer (SES200). The excitation photon is tuned at an appropriate energy for the aim of investigation. Measurements are carried out in a UHV condition. Samples should have electric conductivity to avoid charging. Clean surfaces of the samples are obtained by cleaving or fracture in the UHV chamber.

Source of the figure

No figure

Required time for experimental setup

2 hour(s)

Instruments

Instrument Purpose Performance
Photoemission Spectrometer (PES) angle-integrated photoemission spectroscopy high resolution

References

Document name
Phys. Rev. Lett. 90, 186403 (2003)

Related experimental techniques

Questionnaire

The measurement was possible only in SPring-8. Impossible or very difficult in other facilities.
This solution is an application of a main instrument of the beamline.
Similar experiments account for more than 30% of the beamline's subject.

Ease of measurement

Easy

Ease of analysis

Middle

How many shifts were needed for taking whole data in the figure?

Four-nine shifts

Last modified 2023-03-08 11:12