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How to maximize the superconducting critical temperature in a molecular superconductor(Press Release)

Release Date
18 Apr, 2015
  • BL10XU (High Pressure Research)
Key points
• Discovery of a new state of matter –the Jahn-Teller metal– in which localized electrons on the fullerene molecules co-exist with metallicity
• Emergence of unconventional superconductivity from the Jahn-Teller metal
• Balancing the molecular and itinerant character of the electrons leads to the highest known Tc among molecular superconductors

An international research team, led by Professor Kosmas Prassides of Tohoku University, has investigated the electronic properties of the family of unconventional superconductors based on fullerenes*1 which have the highest known superconducting critical temperature (Tc) among molecular superconductors*2.

In results published in the American scientific journal Science Advances, the team was able to demonstrate the guiding influence of the molecular electronic structure in controlling superconductivity and achieving the maximum Tc, opening the way to new routes in the search of new molecular superconductors with enhanced figures of merit.

Publication Information
Title: "Optimized unconventional superconductivity in a molecular Jahn-Teller metal"
Authors: Ruth H. Zadik, Yasuhiro Takabayashi, Gyöngyi Klupp, Ross H. Colman, Alexey Y. Ganin, Anton Potočnik, Peter Jeglič, Denis Arčon, Péter Matus, Katalin Kamarás, Yuichi Kasahara, Yoshihiro Iwasa, Andrew N. Fitch, Yasuo Ohishi, Gaston Garbarino, Kenichi Kato, Matthew J. Rosseinsky, and Kosmas Prassides
Journal: Science Advances, vol. 1, article number: e1500059 (2015)
DOI: 10.1126/sciadv.1500059

Metals are used for electricity transmission, but energy is lost as heat because of electrical resistance. Superconductors have no electrical resistance and can carry electricity without losing energy, so it is important to find superconductors which can work at the highest possible temperature.

Most superconductors have simple structures built from atoms. But recently, superconductors made from molecules arranged in regular solid structures have been found.
Work by members of the team on molecular fulleride-based systems has previously led to the discovery of the highest working temperature (at 38 K) for a molecular superconductor (Nature Materials 7, p. 367, 2008).

The electronic ground state, which is in competition with superconductivity, was found to be magnetically ordered (Science 323, p. 1585, 2009). And the zero-resistance superconducting state could be switched on by tuning the exact arrangement of the C60 molecules in the solid by external pressure (Nature 466, p. 221, 2010).

The controlling role of the molecular electronic structure was then identified by demonstrating that the parent insulating state involves Jahn-Teller distortion*3 of the molecular anions that produces the magnetism from which the superconductivity emerges (Nature Communications 3, 912, 2012).

The research team has addressed for the first time the relationship between the parent insulator, the normal metallic state above Tc and the superconducting pairing mechanism in a new family of chemically-pressurized fullerene materials. This is a key question in understanding all unconventional superconductors including the high-Tc cuprates, the iron pnictides and the heavy fermion systems.

Their work unveiled a new state of matter – the Jahn-Teller metal – and showed that when the balance between molecular and extended lattice characteristics of the electrons at the Fermi level is optimized, the highest achievable temperature for the onset of superconductivity is attained.

As synthetic chemistry allows the creation of new molecular electronic structures distinct from those in the atoms and ions that dominate most known superconductors, there is now strong motivation to search for new molecular superconducting materials.

The Team
Team Leader Kosmas Prassides is a Professor at Tohoku University’s Advanced Institute for Materials Research, and a former Professor at Durham University, UK. He is an Independent Collaborating Principal Investigator of the JST-supported Isobe Degenerate π-Integration Project of Exploratory Research for Advanced Technology (ERATO). He is also the EU Research Leader of the Light Element Molecular Superconductivity (LEMSUPER) Project, supported under the JST-EU Coordinated Research Project “Superconductivity.”

The Tohoku/Durham group worked with the groups of Professor Yoshihiro Iwasa (Japan Research Leader of LEMSUPER Project) of the University of Tokyo, Professor Denis Arcon of the University of Ljubljana, Slovenia, Professor Katalin Kamaras of the Hungarian Academy of Sciences, and Professor Matthew J. Rosseinsky of the University of Liverpool, UK.

The research utilized the synchrotron radiation X-ray facilities at SPring-8 (Japan) and the ESRF (France).

The results of the study were published in the American Scientific Journal Science Advances.

* Funding program on JST side for this JST-EU coordinated program is “Strategic International Collaborative Research Program, SICORP.”


Fig. 1 Three-dimensional depiction of the crystal structure of the molecular fulleride superconductors investigated in this work.
Fig. 1 Three-dimensional depiction of the crystal structure of the molecular fulleride superconductors investigated in this work.

consist of C60 carbon atoms arranged in a truncated icosahedral shape (a soccer ball) and pack in a regular cubic-close-packed array in three dimensions. Alkali metal ions (blue spheres) occupy vacant interstitial holes of octahedral and tetrahedral symmetry.

Fig. 2 Change in electronic state of the fulleride solids with change in volume per C60.
Fig. 2 Change in electronic state of the fulleride solids with change in volume per C60.

Schematic depictions of the Jahn-Teller molecular distortion of the fullerene units in the Mott-Jahn-Teller insulator (blue molecules) and the Jahn-Teller metal (yellow molecules), their respective molecular electronic structure (lifting of the orbital degeneracy due to the distortion), and the resulting intermolecular hopping of the electrons (prohibited in the insulator, weak hopping in the Jahn-Teller metal). This situation contrasts with the behavior of the conventional metal where hopping is allowed, the orbital degeneracy is retained, and the molecules are undistorted (green molecules).

Fig. 3 Global electronic phase diagram of fulleride solids.
Fig. 3 Global electronic phase diagram of fulleride solids.

Electronic phase diagram of face-centered-cubic (fcc) structured fullerides showing the evolution of the superconducting transition temperature, Tc (superconductivity dome) and the Mott-Jahn-Teller insulator to Jahn-Teller metal crossover temperature, T' as a function of volume per C60. Within the metallic (superconducting) regime, gradient shading from orange to green schematically illustrates the Jahn-Teller metal to conventional metal (unconventional to weak-coupling BCS conventional superconductor) crossover. The inset shows the crystal structure of fcc A3C60 fullerides (A=alkali metal, green spheres represent cations on tetrahedral and red on octahedral holes, respectively).


(*1) Fullerenes
Fullerenes are molecules consisting of an even number of carbon atoms arranged over the surface of a closed hollow cage. C60 (buckminsterfullerene) which has a soccer-ball shape is the archetypal member of the fullerene family and can be considered as the third allotrope of carbon after graphite and diamond. British and American scientists won the Nobel Prize in Chemistry in 1996 for their discovery of the fullerenes.

(*2) Superconductivity
Superconductors have no electrical resistance and can carry electricity without losing energy. The temperature at which the resistance becomes zero is called the critical temperature for the onset of superconductivity, Tc. In superconducting materials, a strong attractive force acts between the electrons, which pair up and can move throughout the material without resistance.

(*3) Jahn-Teller effect
The Jahn-Teller theorem states that for any degenerate electronic state associated with a molecular electronic configuration, there will be some electron-vibrational interaction which lifts the electronic degeneracy and leads to a molecular distortion. A negatively-charged C60 molecular ion can undergo a Jahn–Teller distortion by reshaping its molecular structure away from perfect icosahedral symmetry.

About AIMR
The Advanced Institute for Materials Research (AIMR) at Tohoku University is one of nine World Premier International Research Center Initiative (WPI) Program established with the support of the Japanese Ministry of Education, Culture, Sports, Science and Technology (MEXT), aimed at developing world-class research bases in Japan. Since its establishment in 2007, AIMR has been active in conducting research activities and creating new systems in order to become a global center for materials science. Since 2012, AIMR has also been conducting fundamental research by finding connections between materials science and mathematics.
Learn more at http://www.wpi-aimr.tohoku.ac.jp

《Contact Information》
〈About Research〉
Prof. Prassides Kosmas
Advanced Institute for Materials Research, Tohoku University
E-MAIL :mail1
TEL : +81-22-217-5994
URL: http://www.wpi-aimr.tohoku.ac.jp/prassides_labo/

(About Public Relations)
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